Rhodium-catalyzed Mizoroki-Heck-type arylation of alkenes with aroyl chlorides under phosphane- and base-free conditions

被引：77

作者：

Sugihara, T ^{[1
]}

Satoh, T ^{[1
]}

Miura, M ^{[1
]}

Nomura, M ^{[1
]}

机构：

[1] Osaka Univ, Dept Appl Chem, Fac Engn, Suita, Osaka 5650871, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 38期

关键词：

D O I：

10.1002/anie.200351905

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Simple but effective! Even without the addition of any phosphane ligand and base, alkenes efficiently undergo Mizoroki-Heck-type arylation upon treatment with aroyl chlorides in the presence of a rhodium catalyst (see scheme). The products were isolated by a very simple procedure.

引用

页码：4672 / 4674

页数：3

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