Topochemical photodimerization in the coordination polymer [{(CF3CO2)(μ-O2CCH3)Zn)2(μ-bpe)2]n through single-crystal to single-crystal transformation

被引：251

作者：

Toh, NL ^{[1
]}

Nagarathinam, M ^{[1
]}

Vittal, JJ ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 15期

关键词：

cycloaddition; photochemistry; self-assembly; topochemistry; zinc;

D O I：

10.1002/anie.200462673

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The molecular-ladder-structured, one-dimensional Zn-(4,4′- bipyridylethylene) coordination polymer 1 undergoes [2+2] photochemical cycloaddition across the rails to form 2 in up to 100% yield, accompanied by a single-crystal to single-crystal transformation (Chemical Equation Presented). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2237 / 2241

页数：5

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