Large molecular motions are tolerated in crystals of diamine double salt of trans-chlorocinnamic acids with trans-1,2-diaminocyclohexane

被引：60

作者：

Natarajan, A ^{[1
]}

Mague, JT

Venkatesan, K

Ramamurthy, V

机构：

[1] Univ Miami, Dept Chem, Coral Gables, FL 33124 USA

[2] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA

[3] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 10期

关键词：

D O I：

10.1021/ol050330u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Contrary to the general assumption that photoreactions in crystals may not proceed with large molecular motions, a pedal-like motion prompted by electronic excitation is believed to be involved during the beta-dimer formation from the crystals of the diamine double salt of trans-2,4-dichlorocinnamic acid and trans-1,2-diaminocyclohexane.

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页码：1895 / 1898

页数：4

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