1,2-thiaborolide:: A new heteroaromatic π-ligand containing boron and sulfur

被引:22
作者
Ashe, AJ [1 ]
Fang, XD [1 ]
Kampf, JW [1 ]
机构
[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
关键词
D O I
10.1021/om000815g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The heteroaromatic anion lithium 2-(diisopropylamino)-1,2-thiaborolide (3) has been prepared by a synthesis using the Grubbs ring-closing metathesis. 3 has been converted to the Cp*Ru complex 10, the Cp*ZrCl2 complex 11, and the Me2Si-bridged CpZrCl2 complex 15.
引用
收藏
页码:4935 / 4937
页数:3
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