Boratabenzene analogues of the constrained geometry polymerization catalysts

被引:41
作者
Ashe, AJ [1 ]
Fang, XG [1 ]
Kampf, JW [1 ]
机构
[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
关键词
D O I
10.1021/om990039g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
(4-Dimethylsilyl-tert-butylamido)-N,N-diiso-propyl-1-aminoboratabenzene ZrCl2 (7a) and TiCl2 (7b) complexes have been prepared. When activated by excess methylaluminoxane, 7a and 7b are catalysts for the polymerization. of ethylene.
引用
收藏
页码:1363 / 1365
页数:3
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