(NaLa2)NaPtO6:: The first 2H-perovskite related oxide with a rare earth cation on the A-site

被引：24

作者：

Davis, MJ ^{[1
]}

Smith, MD ^{[1
]}

zur Loye, HC ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 22期

关键词：

D O I：

10.1021/ic034679u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystals of (NaLa2)NaPtO6 were grown in an acidic ("wet") NaOH flux. (NaLa2)NaPtO6 forms in a 2H-perovskite related structure type and contains mixed cation (Na/La) occupancy on the A-site. The crystal was a rhombohedral obverse-reverse twin, and it crystallizes in the space group R (3) over barc (hexagonal setting) with lattice parameters of a = 9.5031(2) Angstrom and c = 11.4625(5) Angstrom. (NaLa2)NaPtO6 is the first example of an m = 0, n = 1 (A(3)A'BO6) member of the A(3n+3m)A'nB3m+nO9m+6n family of oxides where either a lanthanide or a sodium cation occupies the A-site.

引用

页码：6980 / 6982

页数：3

共 27 条

[1]

[Anonymous], 1967, Inorg. Synth, DOI DOI 10.1002/9780470132401

[2] Antimony in the Sr4PtO6 structure:: A neutron diffraction study of Sr3NaSbO6 [J].

Battle, PD ;

Hartwell, SJ ;

Moore, CA .

INORGANIC CHEMISTRY, 2001, 40 (07) :1716-+

[3] STRUCTURAL RELATIONSHIPS BETWEEN COMPOUNDS BASED ON THE STACKING OF MIXED LAYERS RELATED TO HEXAGONAL PEROVSKITE-TYPE STRUCTURES [J].

DARRIET, J ;

SUBRAMANIAN, MA .

JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (04) :543-552

[4] Ca4IrO6, Ca3MgIrO6 and Ca3ZnIrO6 [J].

Davis, MJ ;

Smith, MD ;

zur Loye, HC .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2001, 57 :1234-1236

[5]

ELWELL D, 1975, CRYSTAL GROWTH HIGH, V4

[6] THE ACIDIC AND BASIC PROPERTIES OF OXIDES [J].

FLOOD, H ;

FORLAND, T .

ACTA CHEMICA SCANDINAVICA, 1947, 1 (06) :592-604

[7] On NaBa3RuO6 and NaBa3IrO6. Two noble metal oxometallates showing Sr4PtO6 structure [J].

Frenzen, S ;

MullerBuschbaum, H .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (08) :1204-1206

[8]

GORET J, 1964, B SOC CHIM FR, P1074

[9] A new nickel(III) oxide family: MSr(3)NiO(6) (M=Sc, In, Tm, Yb and Lu) [J].

James, M ;

Attfield, JP .

CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (06) :737-741

[10] PREPARATION, STRUCTURE AND MAGNETIC-PROPERTIES OF A NEW NICKEL(III) OXIDE YBSR3NIO6 [J].

JAMES, M ;

ATTFIELD, JP .

JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (04) :575-578

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