On NaBa3RuO6 and NaBa3IrO6. Two noble metal oxometallates showing Sr4PtO6 structure

被引：21

作者：

Frenzen, S ^{[1
]}

MullerBuschbaum, H ^{[1
]}

机构：

[1] CHRISTIAN ALBRECHTS UNIV KIEL,INST ANORGAN CHEM,D-24098 KIEL,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1996年 / 51卷 / 08期

关键词：

sodium; barium; ruthenium; iridium; oxide; crystal structure;

D O I：

10.1515/znb-1996-0821

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of NaBa3RuO6 (I) and NaBa3IrO6 (II) have been prepared by crystallization from melts in closed silver tubes. The crystal structures were investigated by X-ray techniques. Both compounds crystallize with trigonal (rhombohedral) symmetry, space group D-3d(6) -R (3) over bar c, I: a = 10.107(2), c = 11.872(2) Angstrom, II: a = 10.128(2), c = 11.905(2) Angstrom Z = 6. I and II are isostructural to the Sr4PtO6 type.

引用

页码：1204 / 1206

页数：3

共 17 条

[1] THE STRUCTURAL AND ELECTRONIC-PROPERTIES OF THE RU(V) PEROVSKITES BA2LARU0.5SB0.5O6 AND BA2TARU0.5NA0.5O6 [J].

ALMAER, SA ;

BATTLE, PD ;

LIGHTFOOT, P ;

MELLEN, RS ;

POWELL, AV .

JOURNAL OF SOLID STATE CHEMISTRY, 1993, 102 (02) :375-381

[2] THE CRYSTAL-STRUCTURE AND ELECTRONIC-PROPERTIES OF BA4RU3MO12 (M = LI, NA, MG, ZN) [J].

BATTLE, PD ;

KIM, SH ;

POWELL, AV .

JOURNAL OF SOLID STATE CHEMISTRY, 1992, 101 (01) :161-172

[3] A silver containing phase of an oxoruthenate: Ag0.4Na2.3Ca4.3RuO8 [J].

Frenzen, S ;

MullerBuschbaum, H .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (04) :485-488

[4]

FRENZEN S, 1995, Z NATURFORSCH B, V50, P581

[5] On a new oxoiridate(V) of the Sr4PtO6 type: NaSr3IrO6 [J].

Frenzen, S ;

MullerBuschbaum, H .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (02) :225-228

[6] STRUCTURE AND TWINNING OF SR3CUPTO6 [J].

HODEAU, JL ;

TU, HY ;

BORDET, P ;

FOURNIER, T ;

STROBEL, P ;

MAREZIO, M ;

CHANDRASHEKHAR, GV .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1992, 48 :1-11

[7] PREPARATION AND CHARACTERIZATION OF NEW PEROVISKITES CONTAINING IR(VI) AND IR(V) [BAM0.50IR0.50O.275 AND BAM0.25IR0.75O3 (M=LI OR NA)] [J].

JUNG, DY ;

DEMAZEAU, G ;

ETOURNEAU, J ;

SUBRAMANIAN, MA .

MATERIALS RESEARCH BULLETIN, 1995, 30 (01) :113-123

[8] A NEW STRUCTURE TYPE ON THE 1ST ALKALINE-EARTH-IRIDIUM-COPPER OXIDE - SR3IRCUO6 [J].

NEUBACHER, M ;

MULLERBUSCHBAUM, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1992, 607 (01) :124-127

[9] A FAMILY OF ONE-DIMENSIONAL OXIDES - SR(3)MIRO(6) (M=NI, CU, ZU) - STRUCTURE AND MAGNETIC-PROPERTIES [J].

NGUYEN, TN ;

ZURLOYE, HC .

JOURNAL OF SOLID STATE CHEMISTRY, 1995, 117 (02) :300-308

[10] THE CRYSTAL STRUCTURE OF SR4PTO6 AND 2 RELATED COMPOUNDS [J].

RANDALL, JJ ;

KATZ, L .

ACTA CRYSTALLOGRAPHICA, 1959, 12 (07) :519-521

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