Ultrafast dynamics of the 11Bu-state of 1,3-butadiene after excitation at 204 nm

被引:26
作者
Assenmacher, F
Gutmann, M
Hohlneicher, G
Stert, V
Radloff, W
机构
[1] Univ Cologne, Inst Phys Chem, D-50939 Cologne, Germany
[2] Max Born Inst Nichtlineare Opt & Kurzzeit Spektro, D-12489 Berlin, Germany
关键词
D O I
10.1039/b104013h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The ultrafast dynamics of the 1(1)B(u)-state of 1,3-butadiene was investigated in real time in a femtosecond pump-probe experiment utilizing the RE2PI scheme. A lifetime of 35 +/- 10 fs was found for the 1(1)B(u)-state of the jet-cooled molecule.
引用
收藏
页码:2981 / 2982
页数:2
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