Submerged electric arc between graphite electrodes: a one-pot tool for the synthesis of long-chain polyynes in solution

被引：37

作者：

Cataldo, F ^{[1
]}

机构：

[1] Soc Lupi Chem Res Inst, I-00133 Rome, Italy

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 01期

关键词：

polyynes; ene-ynes; synthesis; electric arc; graphite electrodes;

D O I：

10.1016/j.tetlet.2003.10.100

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Polyynes, a class of molecules described by the general formula H-(CdropC)(m)H (where m is an integer) can be synthesized using an electric arc between graphite electrodes submerged in an organic solvent such as methanol, n-hexane, n-dodecane, decahydronaphthalene or acetonitrile. When the electric are is used in acetonitrile at -40degreesC, polyyne chains of up to 18 carbon atoms (m = 9) have been produced together with monocyanopolyyne as by-product. The polyynes can be reduced to ene-ynes by shaking a hexane solution of them with Zn/HCl. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：141 / 144

页数：4

共 28 条

[1]

[Anonymous], 2000, ROMPP ENCY NATURAL P

[2]

Cataldo F, 1997, POLYM INT, V44, P191, DOI 10.1002/(SICI)1097-0126(199710)44:2<191::AID-PI842>3.0.CO

[3]

2-Y

[4] Simple generation and detection of polyynes in an arc discharge between graphite electrodes submerged in various solvents [J].

Cataldo, F .

CARBON, 2003, 41 (13) :2671-2674

[5] Raman scattering investigation of carbynoid and diamond-like carbon [J].

Cataldo, F .

FULLERENE SCIENCE AND TECHNOLOGY, 2001, 9 (02) :153-160

[6]

Cataldo F, 1999, ANGEW MAKROMOL CHEM, V264, P65

[7]

Cataldo F, 1999, POLYM INT, V48, P15, DOI 10.1002/(SICI)1097-0126(199901)48:1<15::AID-PI85>3.3.CO

[8]

2-R

[9] Synthesis of polyynes (and ene-ynes) segments by dechlorination reactions of chlorinated polyethylene wax and chlorinated docosane [J].

Cataldo, F .

JOURNAL OF MATERIALS SCIENCE, 2000, 35 (10) :2413-2419

[10] Raman spectra and thermal analysis on polyyne and polyene-yne chain segments [J].

Cataldo, F .

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2000, 37 (08) :881-892

← 1 2 3 →