Enantioselective catalysis .101. Synthesis and coordination properties of (3'S,4'S)-(+)-1,2-Bis(3',4'-dimethoxyphospholano)benzene, a new chiral diphosphane

被引：3

作者：

Brunner, H

Net, G

机构：

[1] Inst. für Anorganische Chemie, Universität Regensburg

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1996年 / 51卷 / 08期

关键词：

chiral bisphosphanes; expanded phosphanes; rhodium complexes; cyclic sulfates;

D O I：

10.1515/znb-1996-0823

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new bisphospholane, BDPB, derived from 1,2-bisphosphanobenzene and tartaric acid as well as the complex [Rh(COD)(BDPB)]PF6 were synthesized. The strong binding of BDPB to metals and the presence of four functional groups in the periphery of the molecule make this bisphospholane a good starting point for new expanded bisphosphanes.

引用

页码：1210 / 1212

页数：3

共 17 条

[1] ANALYSIS OF NUCLEAR MAGNETIC RESONANCE SPECTRA .5. ANALYSIS OF DECEPTIVELY SIMPLE SPECTRA [J].