Characterization of sputtered NiO thin films

Nickel oxide (NiO) thin films were deposited by RF magnetron sputtering process at different RF powers and substrate temperatures in a pure oxygen atmosphere. The structural, optical and electrical properties of NiO films were investigated using X-ray diffraction (XRD), visible spectrum and Hall effect measurements. The dependences of film properties on substrate temperature, crystalline structure and natural aging effect were studied. The results show that the resistivity increases as sputtering power increases from 100 to 200 W at constant temperature. The lowest resistivity and Hall coefficient obtained are 16.7 Omega cm and 1.99 cm(3)/C, respectively, as the sputtering power is 100 W and substrate temperature is 350 degrees. The highest carrier concentration obtained is 3.13 X 10(18) cm(-3) as the sputtering power is 100 Wand substrate temperature is 350 degrees. The crystal structure was analyzed by X-ray diffraction method. The preferred orientation of NiO film changes from (111) to (200) when the substrate temperature varies from unheated condition to 350 degrees. Electrical properties of NiO films were unstable and show a natural aging effect. Resistivity of NiO films increases as the time of natural aging increases. Under the substrate-unheated condition, the transmittance of as-deposited samples is lower compared to the film prepared at substrate temperature of 350 degrees C. The change in transmittance may be due to the microstructural change in the material. It is suggested that the sputtering power affects the preferred orientation of NiO film. Higher substrate temperature induces larger grain size and more perfect crystalline structure, which lead to low resistivity of NiO film. (c) 2004 Published by Elsevier B.V.