Highly efficient solvent-free condensation of carboxylic acids with alcohols catalysed by zinc perchlorate hexahydrate, Zn(CIO4)2•6 H2O

被引：48

作者：

Bartoli, G

Boeglin, J

Bosco, M

Locatelli, M

Massaccesi, M

Melchiorre, P

Sambri, L

机构：

[1] Dipartimento Chim Organ A Mangini, I-40136 Bologna, Italy

[2] Univ Strasbourg 1, Strasbourg, France

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2005年 / 347卷 / 01期

关键词：

atom economy; esterification; esters; heterogeneous catalysis; solvent-free; zinc perchlorate;

D O I：

10.1002/adsc.200404171

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Zinc perchlorate hexahydrate, Zn(ClO4)(2)(.) 6 H2O, efficiently catalyses the esterification between nearly equimolar amounts of carboxylic acids and alcohols. The reaction works under solvent-free conditions at relatively low temperatures. Excellent results were obtained with a wide range of substrates.

引用

页码：33 / 38

页数：6

共 26 条

[11] Highly efficient esterification of carboxylic acids with alcohols by montmorillonite-enwrapped titanium as a heterogeneous acid catalyst
Kawabata, T
Mizugaki, T
Ebitani, K
Kaneda, K
[J]. TETRAHEDRON LETTERS, 2003, 44 (51) : 9205 - 9208
[12] KOCIENSKI PJ, 2004, PROTECTING GROUPS, P323
[13] Larock R C, 1999, COMPREHENSIVE ORGANI, P1932
[14] Catalytic esterifications of carboxylic acids and alcohols by sodium bisulfate monohydrate
Li, YQ
[J]. SYNTHETIC COMMUNICATIONS, 1999, 29 (22) : 3901 - 3903
[15] Loupy A, 1999, TOP CURR CHEM, V206, P153
[16] Metzger JO, 1998, ANGEW CHEM INT EDIT, V37, P2975, DOI 10.1002/(SICI)1521-3773(19981116)37:21<2975::AID-ANIE2975>3.0.CO
[17] 2-A
[18] Water-tolerant and reusable catalysts for direct ester condensation between equimolar amounts of carboxylic acids and alcohols
Nakayama, M
Sato, A
Ishihara, K
Yamamoto, H
[J]. ADVANCED SYNTHESIS & CATALYSIS, 2004, 346 (11) : 1275 - 1279
[19] NIKITINA ZK, 1986, ZH NEORG KHIM+, V31, P691
[20] Toward ideal (Trans) esterification by use of fluorous distannoxane catalysts
Otera, J
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2004, 37 (05) : 288 - 296

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