One-electron reduction of an "extended viologen" p-phenylene-bis-4,4′-(1-aryl-2,6-diphenylpyridinium) dication

被引：41

作者：

Funston, A

Kirby, JP

Miller, JR

Pospísil, L

Fiedler, J

Hromadová, M

Gál, M

Pecka, J

Valásek, M

Zawada, Z

Rempala, P

Michl, J

机构：

[1] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA

[2] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

[3] Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem, CR-18223 Prague, Czech Republic

[4] Charles Univ, Dept Organ Chem, Prague, Czech Republic

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2005年 / 109卷 / 48期

关键词：

D O I：

10.1021/jp053556n

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

One-electron reduction of the "extended viologen" dication I yields the red cation radical 2, characterized by strong near-IR absorption. It has been generated and studied by pulse radiolytic, electrochemical, redox titration, UV-visible, and electron paramagnetic resonance spectroscopic methods. All results are in agreement with a fully delocalized electronic structure for 2.

引用

收藏

页码：10862 / 10869

页数：8

相关论文

共 53 条

[11] 1,4-BIS(1,2,6-TRIPHENYL-4-PYRIDYL)BENZENE AS A NOVEL HYDROPHOBIC ELECTRON RELAY FOR DIHYDROGEN EVOLUTION IN PHOTOCATALYTIC SYSTEMS BASED ON LIPID VESICLES [J].

EFIMOVA, EV ;

LYMAR, SV ;

PARMON, VN .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1994, 83 (02) :153-159

[12] Molecular wire formation from viologen assemblies [J].

Haiss, W ;

van Zalinge, H ;

Höbenreich, H ;

Bethell, D ;

Schiffrin, DJ ;

Higgins, SJ ;

Nichols, RJ .

LANGMUIR, 2004, 20 (18) :7694-7702

[13] AROMATIC POLY(PYRIDINIUM SALT)S - SYNTHESIS AND STRUCTURE OF ORGANO-SOLUBLE, RIGID-ROD POLY(PYRIDINIUM TETRAFLUOROBORATE)S [J].

HARRIS, FW ;

CHUANG, KC ;

HUANG, SAX ;

JANIMAK, JJ ;

CHENG, SZD .

POLYMER, 1994, 35 (23) :4940-4948

[14] INTERFACIAL INTERACTIONS AND THE HETEROGENEOUS ONE-ELECTRON REDUCTION OF METHYL VIOLOGEN [J].

HEYROVSKY, M ;

NOVOTNY, L .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1987, 52 (05) :1097-1114

[15] BASE-CATALYZED ALKYLATION OF CYCLOPENTADIENE RINGS WITH ALCOHOLS AND AMINES [J].

HIRSCH, SS ;

BAILEY, WJ .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (21) :4090-4094

[16] Aromatic poly(pyridinium salt)s Part 2. Synthesis and properties of organo-soluble, rigid-rod poly(pyridinium triflate)s [J].

Huang, SAX ;

Chuang, KC ;

Cheng, SZD ;

Harris, FW .

POLYMER, 2000, 41 (13) :5001-5009

[17] INTRAMOLECULAR ASSOCIATION OF VIOLOGEN DIMER AND TRIMER RADICAL CATIONS - AN ELECTROCHEMICAL AND SPECTROSCOPIC STUDY [J].

IMABAYASHI, S ;

KITAMURA, N ;

TOKUDA, K ;

TAZUKE, S .

CHEMISTRY LETTERS, 1987, (05) :915-918

[18] SUBSTITUENT EFFECTS ON ELECTROCHEMICAL REDUCTION OF VIOLOGEN DIMER AND TRIMER WITH ETHYLENE SPACER [J].

IMABAYASHI, SI ;

KITAMURA, N ;

TAZUKE, S ;

TOKUDA, K .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 239 (1-2) :397-403

[19] INFRARED-SPECTRA AND DIMER STRUCTURE OF REDUCED VIOLOGEN COMPOUNDS [J].

ITO, M ;

SASAKI, H ;

TAKAHASHI, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (15) :3932-3934

[20] Dodecamethylcarba-closo-dodecaborate(-) anion, CB(11)Me(12)(-) [J].

King, BT ;

Janousek, Z ;

Gruner, B ;

Trammell, M ;

Noll, BC ;

Michl, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (13) :3313-3314

← 1 2 3 4 5 6 →