Pyrrolidino [60] and [70]fullerene homo- and heterodimers as electron acceptors for OPV

被引:11
作者
Erten-Ela, Sule [1 ,2 ]
Villegas, Carmen [1 ]
Luis Delgado, Juan [3 ]
Martin, Nazario [1 ,3 ]
机构
[1] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Organ, E-28040 Madrid, Spain
[2] Ege Univ, Solar Energy Inst, TR-35100 Izmir, Turkey
[3] IMDEA Nanociencia, Madrid 28049, Spain
关键词
OPEN-CIRCUIT VOLTAGE; AZOMETHINE YLIDES; FULLERENES; STATES;
D O I
10.1039/c4nj01709a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New [60] and [70]fullerene homo-and heterodimers absorbing in the visible region have been synthesized and fully characterized. In order to increase the solubility and processability of the new fullerene dimers, different alkyl chains have been used which has allowed the determination of the influence of the solubilizing alkyl groups on the photovoltaic performance. Atomic force microscopy experiments carried out on blends of these dimers and P3HT evidenced the formation of large aggregates, which significantly influence the photovoltaic efficiency.
引用
收藏
页码:1477 / 1482
页数:6
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