Characterization of chiral mesoporous materials by transmission electron microscopy

被引:110
作者
Ohsuna, T [1 ]
Liu, Z
Che, SN
Terasaki, O
机构
[1] Stockholm Univ, Arrhenius Lab, S-10961 Stockholm, Sweden
[2] Bussan Nanotech Res Inst, Tsukuba, Ibaraki 3050074, Japan
[3] Shanghai Jiao Tong Univ, Dept Chem, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China
关键词
chirality; mesoporous materials; modeling; silica; transmission electron; microscopy;
D O I
10.1002/smll.200400048
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By using transmission electron microscopy (TEM), the chirality of novel mesoporous materials has been studied. In addition, a computer simulation that uses a simple structural model was employed. The existence of chiral channels inside a tubelike material was confirmed by the observation of fringes along the length of the tubes. The chiral pitch of the channels was measured from the intermittent period, the chirality (right-or left-handed) was determined from the tilt direction of a tube compared with the direction of incident electrons and the curvature direction of the curved intermitted fringes as viewed in the TEM images.
引用
收藏
页码:233 / 237
页数:5
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