One-dimensional nanoporous M2L2 rhombohedral molecular square with strong blue fluorescent emission

被引：27

作者：

Li, YX

Li, YH

Zeng, XR

Xiong, RG ^{[1
]}

You, XZ

Fun, HK

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China

[2] Beijing Univ, State Key Lab Rare Earth Mat Chem & Applicat, Dept Chem, Beijing 100871, Peoples R China

[3] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 08期

基金：

中国国家自然科学基金;

关键词：

rhombic molecular square; nano-sized; Zn and Cd; coordination polymer;

D O I：

10.1016/S1387-7003(03)00181-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reactions of Zn(ClO4)(2).6H(2)O and Cd(ClO4)(2) . 6H(2)O with the ligand N,N'-bis(pyridylcarbonyl)-4,4'-diaminodiphenyl ether (L) afford two one-dimensional (1D) coordination polymers, ([CdL(ClO4)(2).(H2O)(2)].2H(2)O) (1) and [ZnL(ClO4)(2) . (H2O)(2)].2H(2)O, (2) having a nanoporous M2L2 rhombohedral molecular square with an approximately accessible cavity of 12.9 x 12.9 (1) and 12.7 x 12.7 (2) Angstrom without any interpenetrations. Both 1 and 2 are isostructural and display very strong blue fluorescent emission in the solid state at room temperature. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：1144 / 1147

页数：4

共 53 条

[1] Hydrogen-bond recognition of cyclic dipeptides in water [J].