Analytical mass spectrometry of herbicides

被引:36
作者
Budde, WL [1 ]
机构
[1] US EPA, Off Res & Dev, Cincinnati, OH 45268 USA
关键词
herbicide; chemical structure; mass spectrometry; electron ionization; electrospray; atmospheric pressure chemical ionization; gas chromatography; reversed-phase liquid chromatography; capillary electrophoresis;
D O I
10.1002/mas.10070
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Herbicides are chemical substances that are applied to agricultural soils, gardens, lawns, or plants to destroy or to prevent the growth of undesirable vegetation. The herbicides included in this review are generally synthetic organic compounds that are ingredients in commercial herbicide products that were designated active during late 2002 in the U.S. Environmental Protection Agency's database of registered and canceled pesticide products. The compounds are organized into 21 categories according to their general chemical structures or a common structural group. The herbicides in each category are discussed in terms of their structures, their database electron ionization mass spectra, and their amenability to separation and measurement with gas chromatography, reversed-phase liquid chromatography, and capillary electrophoresis combined with mass spectrometry. Ionization techniques that are considered here are mainly electron ionization, electrospray, and atmospheric pressure chemical ionization. Sixty-six references are provided to herbicide reviews, and to the recent herbicide analytical chemistry and mass spectrometry research literature. (C) 2003 Wiley Periodicals, Inc.
引用
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页码:1 / 24
页数:24
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