Dihydrobis(4-cyano-3-phenylpyrazol-1-yl)borate: Homoleptic mononuclear cobalt(II) and copper(II) complexes with a cyano-substituted scorpionate ligand

被引：19

作者：

Siemer, CJ

Goswami, N

Kahol, PK

Van Stipdonk, MJ

Eichhorn, DM

机构：

[1] Wichita State Univ, Dept Chem, Wichita, KS 67260 USA

[2] Wichita State Univ, Dept Phys, Wichita, KS 67260 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 16期

关键词：

D O I：

10.1021/ic010316n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dihydrobis(4-cyano-3-phenylpyrazol-1-yl)borate: Homoleptic Mononuclear Cobalt(II) and Copper(II) Complexes with a Cyano-Substituted Scorpionate Ligand A bulky phenyl substituent in the 3-position prevents coordination of the cyano group and allows isolation of the first homoleptic mononuclear complexes of a cyano- substituted bis(pyrazolyl)borate ligand.

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页码：4081 / +

页数：5

相关论文

共 36 条

[1] SYNTHESIS OF CHELATING BIDENTATE ISOCYANO AND CYANO LIGANDS AND THEIR METAL-COMPLEXES [J].

ANGELICI, RJ ;

QUICK, MH ;

KRAUS, GA ;

PLUMMER, DT .

INORGANIC CHEMISTRY, 1982, 21 (06) :2178-2184

[2] ASSEMBLY AND CHARACTERIZATION OF AN ACCURATE MODEL FOR THE DIIRON CENTER IN HEMERYTHRIN [J].

ARMSTRONG, WH ;

SPOOL, A ;

PAPAEFTHYMIOU, GC ;

FRANKEL, RB ;

LIPPARD, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (12) :3653-3667

[3] SYNTHESIS OF AN AIR-STABLE, MOISTURE-STABLE, AND THERMALLY STABLE TUNGSTEN(VI) OXO ALKYLIDENE COMPLEX - PRECURSOR TO AN AIR-STABLE AND MOISTURE-STABLE ROMP CATALYST [J].

BLOSCH, LL ;

ABBOUD, K ;

BONCELLA, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (18) :7066-7068

[4] Ethylene oxide and propylene sulfide complexes of silver(I):: Synthesis and characterization of [HB(3,5-(CF3)2Pz)3]Ag(OC2H4) and [HB(3,5-(CF3)2Pz)3]Ag(SC3H6) [J].

Dias, HVR ;

Wang, ZY .

INORGANIC CHEMISTRY, 2000, 39 (16) :3724-+

[5] Direct synthesis of a bis(pyrazolyl)boratocopper(I) complex:: Synthesis and characterization of [H2B(3,5-(CF3)2Pz)2]Cu(PPh3)2 displaying an unusual coordination mode for a poly(pyrazolyl)borate ligand [J].

Dias, HVR ;

Lu, HL .

INORGANIC CHEMISTRY, 2000, 39 (10) :2246-+

[6] SYNTHESIS AND CHEMISTRY OF [HYDRIDOTRIS(3-TERT-BUTYLPYRAZOLYL)BORATO]INDIUM(I) [J].

DIAS, HVR ;

HUAI, L ;

JIN, WC ;

BOTT, SG .

INORGANIC CHEMISTRY, 1995, 34 (08) :1973-1974

[7] Synthesis and chemistry of [hydrotris(3,5-bis(trifluoromethyl)pyrazolyl)borato]silver(I) complexes [J].

Dias, HVR ;

Wang, ZY ;

Jin, WC .

INORGANIC CHEMISTRY, 1997, 36 (27) :6205-6215

[8] Synthesis and characterization of copper(II), zinc(II), and potassium complexes of a highly fluorinated bis(pyrazolyl)borate ligand [J].

Dias, HVR ;

Gorden, JD .

INORGANIC CHEMISTRY, 1996, 35 (02) :318-324

[9]

DIAS HVR, 1995, INORG CHEM, V34, P21

[10] M(HYDROTRIS(3-PHENYLPYRAZOL-1-YL)BORATE)2 - STERICALLY ENCUMBERED IRON(II) AND MANGANESE(II) COMPLEXES [J].

EICHHORN, DM ;

ARMSTRONG, WH .

INORGANIC CHEMISTRY, 1990, 29 (18) :3607-3612

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