SiC/C multi-layered coating contributing to the antioxidation of C/C composites and the suppression of through-thickness cracks in the layer

被引:52
作者
Aoki, T
Hatta, H
Hitomi, T
Fukuda, H
Shiota, I
机构
[1] Sci Univ Tokyo, Fac Ind Sci & Technol, Dept Mat Sci & Technol, Noda, Chiba 2788510, Japan
[2] Inst Space & Astronaut Sci, Sagamihara, Kanagawa 2298510, Japan
[3] Kogakuin Univ, Dept Chem Engn, Hachioji, Tokyo 1928510, Japan
关键词
carbon/carbon composites; chemical vapor deposition; coating; oxidation;
D O I
10.1016/S0008-6223(00)00276-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Silicon carbide/carbon multi-layered coatings have been formed on the surfaces of C/C composites. The multi-layered coatings were deposited by the CVD method at 1200 degreesC using SiCl4 C3H8 and H-2 gases. The principal idea of the present multi-layered coatings is to suppress the through-the-thickness coating cracks by making the thickness of each SiC and carbon layer lower than the corresponding critical thicknesses, h(c)s. The values of h(c)s for the SiC and carbon coatings were 0.2 mum and above 15 mum, respectively. The role of the SiC layers is oxidation protection and that of the carbon layers is to mechanically isolate each SIC layer. Based on theoretical and experimental discussions, the SiC/C multi-layered coating was shown to successfully suppress the through-thickness coating cracks. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1477 / 1483
页数:7
相关论文
共 29 条
[21]   BORATE TREATMENT OF CARBON-FIBERS AND CARBON-CARBON COMPOSITES FOR IMPROVED OXIDATION RESISTANCE [J].
MCKEE, DW .
CARBON, 1986, 24 (06) :737-741
[22]  
NAGAO H, 1999, TANSO, V186, P7
[23]   Chemical reactivity in the processing and the interactions with the environment of ceramic matrix composites [J].
Naslain, RR .
SOLID STATE IONICS, 1997, 101 :959-973
[24]   FINITE-ELEMENT CALCULATION OF STRESS INTENSITY FACTORS BY A MODIFIED CRACK CLOSURE INTEGRAL [J].
RYBICKI, EF ;
KANNINEN, MF .
ENGINEERING FRACTURE MECHANICS, 1977, 9 (04) :931-938
[25]  
Shiosaki T., 1995, P 1995 YOK INT GAS T, P93
[26]   Oxidation protection of carbon-carbon composites by sol-gel ceramic coatings [J].
Stuecker, JN ;
Hirschfeld, DA ;
Martin, DS .
JOURNAL OF MATERIALS SCIENCE, 1999, 34 (22) :5443-5447
[27]  
THOMAS CR, 1993, ESSENTIALS CARBON CA, P143
[28]   CRACK SPACING IN BRITTLE FILMS ON ELASTIC SUBSTRATES [J].
THOULESS, MD .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1990, 73 (07) :2144-2146
[29]   MORPHOLOGICAL DESCRIPTION OF COATING CRACKS IN SIC COATED CARBON-CARBON COMPOSITES [J].
YURGARTIS, SW ;
BUSH, MD ;
MAST, BE .
SURFACE & COATINGS TECHNOLOGY, 1994, 70 (01) :131-142