Unusual alkyl group activation and cationic complex formation from a novel lutetium dialkyl complex supported by a tridentate monoanionic ligand

被引:62
作者
Cameron, TM
Gordon, JC
Michalczyk, R
Scott, BL
机构
[1] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87544 USA
[2] Los Alamos Natl Lab, Biosci Div, NIH Stable Isotope Resource, Los Alamos, NM USA
关键词
D O I
10.1039/b306889g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report herein the synthesis and characterization of a lutetium dialkyl complex supported by a multidentate, anilido-pyridine-imine ligand and its subsequent transformation into an unprecedented cationic monoalkyl derivative.
引用
收藏
页码:2282 / 2283
页数:2
相关论文
共 33 条
  • [11] Organo-rare-earth complexes supported by chelating diamide ligands
    Estler, F
    Eickerling, G
    Herdtweck, E
    Anwander, R
    [J]. ORGANOMETALLICS, 2003, 22 (06) : 1212 - 1222
  • [12] From monomeric to polymeric manganese complexes bearing bis(imino)pyridine and related ligands
    Gibson, VC
    McTavish, S
    Redshaw, C
    Solan, GA
    White, AJP
    Williams, DJ
    [J]. DALTON TRANSACTIONS, 2003, (02) : 221 - 226
  • [13] Titanium hydrocarbyl complexes with a linked cyclopentadienyl-alkoxide ancillary ligand; Participation of the ligand in an unusual activation of a (trimethylsilyl)methyl group
    Gielens, EECG
    Tiesnitsch, JY
    Hessen, B
    Teuben, JH
    [J]. ORGANOMETALLICS, 1998, 17 (09) : 1652 - 1654
  • [14] Gunko YK, 1996, COORDIN CHEM REV, V156, P1
  • [15] A new chelating anilido-imine donor related to β-diketiminato ligands for stabilization of organoyttrium cations
    Hayes, PG
    Welch, GC
    Emslie, DJH
    Noack, CL
    Piers, WE
    Parvez, M
    [J]. ORGANOMETALLICS, 2003, 22 (08) : 1577 - 1579
  • [16] NEW COORDINATIVELY UNSATURATED LUTETIUM MONO(ALKYL) AND BIS(ALKYL) COMPLEXES WITH A BIS(ORTHO)-CHELATING ARYLDIAMINE LIGAND - CRYSTAL-STRUCTURES OF [LUCL2(2,6-(ME(2)NCH(2))(2)C6H3)(MU-CL)(MU-LI(THF)(2))](2) AND [LU(MU-CL)(2,6-(ME(2)NCH(2))(2)C6H3)(CH(2)SIME(3))](2)
    HOGERHEIDE, MP
    GROVE, DM
    BOERSMA, J
    JASTRZEBSKI, JTBH
    KOOIJMAN, H
    SPEK, AL
    VANKOTEN, G
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 1995, 1 (06) : 343 - 350
  • [17] Highly stereoselective intramolecular hydroamination/cyclization of conjugated aminodienes catalyzed by organolanthanides
    Hong, SW
    Marks, TJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (27) : 7886 - 7887
  • [18] Recent developments in organolanthanide polymerization catalysts
    Hou, ZM
    Wakatsuki, Y
    [J]. COORDINATION CHEMISTRY REVIEWS, 2002, 231 (1-2) : 1 - 22
  • [19] KATHERINE S, 1989, ORGANOMETALLICS, V8, P2068
  • [20] KILIMANN U, 1995, COORDIN CHEM REV, V141, P1