Intramolecular acylation of aryl- and aroyl-aliphatic acids by the action of pyrophosphoryl chloride and phosphorus oxychloride

被引：19

作者：

El-Sayrafi, S ^{[1
]}

Rayyan, S ^{[1
]}

机构：

[1] Birzeit Univ, Dept Chem, Birzeit, Israel

来源：

MOLECULES | 2001年 / 6卷 / 03期

关键词：

pyrophosphoryl chloride; phosphorus oxychloride; cyclodehydration; cyclic ketones; anthraquinones;

D O I：

10.3390/60300279

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Both pyrophosphoryl chloride and phosphorus oxychloride react: with aryl aliphatic acids to form mixed anhydrides which undergo intramolecular acylation to afford cyclic ketones without the addition of a Friedel-Crafts catalyst. Aryl and aroyl-benzoic acids could be cyclized to the corresponding anthrones and anthraquinones respectively.

引用

页码：279 / 286

页数：8

共 17 条

[11] Syntheses of alkylphenanthrenes. Part I. 1-, 2-, 3-, and 4-methylphenanthrenes. [J].