Planar para-phenylene oligomers

被引:56
作者
Grimme, J
Scherf, U
机构
[1] Max-Planck-Inst. F. Polymerforschung, D-55128 Mainz
关键词
D O I
10.1002/macp.1996.021970720
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Planar, methylene-bridged quinque- and septiphenyl oligomers were synthesized as soluble, hitherto unknown compounds. The series of homologous and planar ladder-type oligophenyls (ter-, quinque-, septiphenyl) was characterized especially with respect to their optical properties (absorption and emission) as function of increasing chain length, and compared to the corresponding ladder-type polyphenylene. An effective conjugation length of about 12 benzene rings was determined within this series of planar oligo- and polyphenylenes.
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页码:2297 / 2304
页数:8
相关论文
共 14 条
  • [11] SCHERF U, 1992, SYNTHESIS-STUTTGART, P23
  • [12] SCHERF U, 1991, MAKROMOL CHEM-RAPID, V12, P489
  • [13] TOLBERT LM, 1992, ACCOUNTS CHEM RES, V25, P561, DOI 10.1021/ar00024a003
  • [14] TOSI C, 1968, ADV POLYM SCI, V5, P493