From Pincers to Steps: Synthesis, Structure, Characterization, and Transformation of a New Helical Calcium-Organic Framework, Ca[NC5H3(CO2)2](H2O)1.5

被引：27

作者：

Kim, Min Kyung ^{[1
]}

Bae, Kyung-Lyul ^{[1
]}

Ok, Kang Min ^{[1
]}

机构：

[1] Chung Ang Univ, Dept Chem, Seoul 156756, South Korea

来源：

CRYSTAL GROWTH & DESIGN | 2011年 / 11卷 / 04期

关键词：

BOND-VALENCE PARAMETERS; HYBRID FRAMEWORKS; CRYSTAL-STRUCTURE; BUILDING-BLOCKS; COORDINATION; DESIGN; STORAGE; CHAINS; MOF;

D O I：

10.1021/cg101558e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unprecedented 1-D helical calcium organic framework material, Ca[NC5H3(CO2)(2)](H2O)(1.5), has been synthesized for the first time under hydrothermal reaction conditions using Ca(OH)(2), 2,6-NC5H3(CO2H)(2), (CH3)(2)-NCOH, HNO3, and H2O as reagents. A complete characterization including the transformation of the helical chain with pincers to another helix with steps by the reaction with water is reported.

引用

页码：930 / 932

页数：3

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