7Li NMR Study of Li Intercalated Carbons Prepared by Electrochemical Method

被引:3
作者
Kim, Jong Hyun [1 ]
Kim, Jong Hun [1 ]
Barsoukov, Evgenij [1 ]
Yoon, Chul Oh [1 ]
Lee, Hosull [1 ]
机构
[1] Korea Kumho Petrochem Co, Kumho Chem Labs, Taejon 305600, South Korea
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1998年 / 310卷
关键词
(7)Li NMR; lithium intercalation; carbon and graphite;
D O I
10.1080/10587259808045352
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
(7)Li solid-state nuclear magnetic resonance (NMR) is employed to investigate the mechanism of electrochemical lithium-intercalation in various carbon materials. Multiple resonance line shapes observed in fully lithiated carbons indicate that several intercalant sites exist under distinct spin-interaction environment, and they are substantially dependent upon physical nature of host structure. The temperature dependence of resonance spectra in disordered carbons prepared at relatively low carbonization temperature considerably differs from that observed in lithiated carbons with graphite structure.
引用
收藏
页码:297 / 302
页数:6
相关论文
共 16 条
  • [11] Li-7 NMR studies on a lithiated non-graphitizable carbon fibre at low temperatures
    Tatsumi, K
    Conard, J
    Nakahara, M
    Menu, S
    Lauginie, P
    Sawada, Y
    Ogumi, Z
    [J]. CHEMICAL COMMUNICATIONS, 1997, (07) : 687 - 688
  • [12] Li-7-nuclear magnetic resonance observation of lithium insertion into mesocarbon microbeads
    Tatsumi, K
    Akai, T
    Imamura, T
    Zaghib, K
    Iwashita, N
    Higuchi, S
    Sawada, Y
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (06) : 1923 - 1930
  • [13] Electrochemical insertion of lithium into carbon synthesized from condensed aromatics
    Tokumitsu, K
    Mabuchi, A
    Fujimoto, H
    Kasuh, T
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (07) : 2235 - 2239
  • [14] STRUCTURE AND PROPERTIES OF DEEPLY LI-DOPED POLYACENIC SEMICONDUCTOR-MATERIALS BEYOND C6LI STAGE
    YATA, S
    KINOSHITA, H
    KOMORI, M
    ANDO, N
    KASHIWAMURA, T
    HARADA, T
    TANAKA, K
    YAMABE, T
    [J]. SYNTHETIC METALS, 1994, 62 (02) : 153 - 158
  • [15] 1996, P 8 INT M LITH BATT
  • [16] [No title captured]