Electropolymerized Pd-containing thiophene polymer: A reusable supported catalyst for cross-coupling reactions

被引：25

作者：

Albano, Vincenzo G.

Bandini, Marco

Moorlag, Carolyn

Piccinelli, Fabio

Pietrangelo, Agostino

Tommasi, Simona

Umani-Ronchi, Achille

Wolf, Michael O.

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

[2] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 18期

关键词：

D O I：

10.1021/om070210l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electrodeposition of Pd-containing oligothienyl complexes on porous graphite electrodes allows the preparation of a new, reusable heterogeneous organometallic catalyst for intra-as well as intermolecular cross-coupling reactions.

引用

页码：4373 / 4375

页数：3

共 31 条

[11] Selected patented cross-coupling reaction technologies [J].

Corbet, Jean-Pierre ;

Mignani, Gerard .

CHEMICAL REVIEWS, 2006, 106 (07) :2651-2710

[12]

DEMEIJERE A, 2004, MATAL CATALYZED CROS

[13] Intermolecular interactions in conjugated oligothiophenes.: 1.: Optical spectra of terthiophene and substituted terthiophenes recorded in various environments [J].

DiCésare, N ;

Belletête, M ;

Marrano, C ;

Leclerc, M ;

Durocher, G .

JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (07) :795-802

[14] The asymmetric intramolecular Heck reaction in natural product total synthesis [J].

Dounay, AB ;

Overman, LE .

CHEMICAL REVIEWS, 2003, 103 (08) :2945-2963

[15] The art of meeting palladium specifications in active pharmaceutical ingredients produced by Pd-catalyzed reactions [J].

Garrett, CE ;

Prasad, K .

ADVANCED SYNTHESIS & CATALYSIS, 2004, 346 (08) :889-900

[16] EFFECTS OF PHENANTHROLINE TYPE LIGANDS ON THE DYNAMIC PROCESSES OF (ETA(3)-ALLYL)PALLADIUM COMPLEXES - MOLECULAR-STRUCTURE OF (2,9-DIMETHYL-1,10-PHENANTHROLINE)[(1,2,3-ETA)-3-METHYL-2-BUTENYL]-CHLOROPALLADIUM [J].

HANSSON, S ;

NORRBY, PO ;

SJOGREN, MPT ;

AKERMARK, B ;

CUCCIOLITO, ME ;

GIORDANO, F ;

VITAGLIANO, A .

ORGANOMETALLICS, 1993, 12 (12) :4940-4948

[17] Syntheses, structures and redox properties of new macrocyclic triazatriolefinic Pd0 complexes and their polypyrrole modified electrodes -: Application to heterogeneous catalytic Suzuki cross-coupling [J].

Llobet, A ;

Masllorens, E ;

Rodríguez, M ;

Roglans, A ;

Benet-Buchholz, J .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (08) :1601-1610

[18] The effect of Pd(II) coordination on the properties of an alkylsulfanyl substituted polythiophene. Comparison with the corresponding monomer [J].

Mucci, A ;

Parenti, F ;

Pigani, L ;

Seeber, R ;

Zanardi, C ;

Pilo, MI ;

Spano, N ;

Manassero, M .

JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (06) :1287-1292

[19] FURTHER NMR-STUDIES OF DYNAMIC STEREOCHEMISTRY OF PI-ALLYLIC PALLADIUM(II) - TERTIARY PHOSPHINE SYSTEMS [J].

OSLINGER, M ;

POWELL, J .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1973, 51 (02) :274-287

[20] Towards the preparation of modified chiral electrodes for heterogeneous asymmetric catalysis:: synthesis and electrochemical properties of (S,S)-5,5′-bis-[3-(3-methyl-pentyl)-thiophen-2-yl]-[2,2′]-bipyridine [J].

Papillon, J ;

Schulz, E ;

Gelinas, S ;

Lessard, J ;

Lemaire, M .

SYNTHETIC METALS, 1998, 96 (02) :155-160

← 1 2 3 4 →