Parent Heavy Methylenes: Chemical Tricks to Access Isolable Complexes of Elusive H2E: Species (E = Ge and Sn)

被引：32

作者：

Inoue, Shigeyoshi ^{[1
]}

Driess, Matthias ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Chem Anorgan Chem Met Organ Chem & Anorgan M, D-1000 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 25期

关键词：

carbenes; germanium; main-group elements; metallenes; tin; METAL ALKYLS; TIN; COMPOUND; AMIDES;

D O I：

10.1002/anie.201101812

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A milestone in main-group chemistry: Elusive heavy methylene analogues:EH2 (E=Ge and Sn) were tamed to give isolable species. This feat was achieved by applying the concept of donor-acceptor stabilization: concomitant coordination of a transition metal or monoborane as a Lewis acid and of an N-heterocyclic carbene as a Lewis base (see scheme). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5614 / 5615

页数：2

共 33 条

[1] Stabilization of the Heavy Methylene Analogues, GeH2 and SnH2, within the Coordination Sphere of a Transition Metal [J].

Al-Rafia, S. M. Ibrahim ;

Malcolm, Adam C. ;

Liew, Sean K. ;

Ferguson, Michael J. ;

Rivard, Eric .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (04) :777-779

[2]

[Anonymous], 2009, Angew. Chem.

[3]

[Anonymous], 2009, ANGEW CHEM

[4] N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands [J].

Asay, Matthew ;

Jones, Cameron ;

Driess, Matthias .

CHEMICAL REVIEWS, 2011, 111 (02) :354-396

[5] Nonmetal-Mediated Fragmentation of P4: Isolation of P1 and P2 Bis(carbene) Adducts [J].

Back, Olivier ;

Kuchenbeiser, Glenn ;

Donnadieu, Bruno ;

Bertrand, Guy .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (30) :5530-5533

[6] SUB-VALENT GROUP 4B METAL ALKYLS AND AMIDES .1. SYNTHESIS AND PHYSICAL-PROPERTIES OF KINETICALLY STABLE BIS[BIS(TRIMETHYSILYL)METHYL]-GERMANIUM(II), BIS[BIS(TRIMETHYSILYL)METHYL]-TIN(II), AND BIS[BIS(TRIMETHSILYL)METHYL]-LEAD(II) [J].

DAVIDSON, PJ ;

HARRIS, DH ;

LAPPERT, MF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (21) :2268-2274

[7]

Driess M, 1996, ANGEW CHEM INT EDIT, V35, P829

[8]

Driess M., 1996, Angew. Chem, V108, P900

[9]

Fischer E.O., 1973, NOBEL LECT 1211

[10]

Fischer E.O., 1974, ANGEW CHEM-GER EDIT, V86, P651

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