Parent Heavy Methylenes: Chemical Tricks to Access Isolable Complexes of Elusive H2E: Species (E = Ge and Sn)

被引：32

作者：

Inoue, Shigeyoshi ^{[1
]}

Driess, Matthias ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Chem Anorgan Chem Met Organ Chem & Anorgan M, D-1000 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 25期

关键词：

carbenes; germanium; main-group elements; metallenes; tin; METAL ALKYLS; TIN; COMPOUND; AMIDES;

D O I：

10.1002/anie.201101812

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A milestone in main-group chemistry: Elusive heavy methylene analogues:EH2 (E=Ge and Sn) were tamed to give isolable species. This feat was achieved by applying the concept of donor-acceptor stabilization: concomitant coordination of a transition metal or monoborane as a Lewis acid and of an N-heterocyclic carbene as a Lewis base (see scheme). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5614 / 5615

页数：2