Fluorothiolate-dithioacid complexes of ruthenium(III) and osmium(III):: crystal structure of [Os(SC6F5)2(S2CNEt2)(PMe2Ph)2]

被引：8

作者：

Arroyo, M

Bernès, S

Meléndez, L

Richards, RL

Torrens, H

机构：

[1] BUAP, Inst Ciencias, Ctr Quim, Puebla 72571, Mexico

[2] John Innes Ctr Plant Sci Res, Nitrogen Fixat Lab, Norwich NR4 7UH, Norfolk, England

[3] Univ Nacl Autonoma Mexico, Fac Quim, Div Estudios Posgrado, Mexico City 04510, DF, Mexico

来源：

TRANSITION METAL CHEMISTRY | 2001年 / 26卷 / 06期

关键词：

D O I：

10.1023/A:1012023309460

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the coordinative unsaturated complexes [M(SRF)(3)(PMe2Ph)(2)] (M = Os or Ru; R-F = C6F5 or C6F4H-4) with M'S(2)Z (M' = Na, S(2)Z = S2CNEt2; M' = K, S(2)Z = S2COEt) and [Os(SRF)(3)(PMe2Ph)(2)] (R-F = C6F5 or C6F4H-4) with M'S(2)Z [M' = Na; S(2)Z = S2P(OEt)(2)] in Me2CO solution, gave the paramagnetic Os-III and Ru-III derivatives, [M(SRF)(2)(S(2)Z)(PMe2Ph)(2)]. X-ray crystallography shows that [Os(SC6F5)(2)(S2CNEt2)(PMe2Ph)(2)] has an octahedral geometry with trans-fluorothiolates, cis-phosphines and a chelating N,N-diethyldithiocarbamate ligand.

引用

页码：608 / 612

页数：5

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