[Ni(phen)3]2Sb18S29: A Novel Three-Dimensional Framework Thioantimonate(III) Templated by [Ni(phen)3] Complexes

被引：38

作者：

Du, Ke-Zhao ^{[1
,2
]}

Feng, Mei-Ling ^{[1
]}

Li, Long-Hua ^{[1
]}

Hu, Bing ^{[1
]}

Ma, Zu-Ju ^{[1
,2
]}

Wang, Peng ^{[1
,2
]}

Li, Jian-Rong ^{[1
]}

Wang, Yu-Long ^{[1
,2
]}

Zou, Guo-Dong ^{[1
,2
]}

Huang, Xiao-Ying ^{[1
]}

机构：

[1] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

INORGANIC CHEMISTRY | 2012年 / 51卷 / 07期

关键词：

SOLVOTHERMAL SYNTHESIS; ANTIMONY-SULFIDE; METAL-COMPLEXES; OPTICAL-PROPERTIES; CRYSTAL-STRUCTURES; FE; NI; CHANNELS; CATIONS; AMINES;

D O I：

10.1021/ic202246q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel thioantimonate(III), namely, [Ni(phen)(3)](2)Sbi(8)S(29) (1; phen = 1,10-phenanthroline), has been solvothermally synthesized. Its structure features a three-dimensional framework with the largest channels in thioantimonates. The chiral [Ni(phen)(3)](2+) cations and the Sb:S ratio (1:1.611) in I are unique among those in the reported thioantimonates. The thermal stability, optical properties, and electric conductivity as well as the theoretical band structure and density of state of I have also been studied.

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页码：3926 / 3928

页数：3

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