The synthesis and characterisation of four new antimony sulphides incorporating transition-metal complexes

被引：27

作者：

Lees, Rachel J. E.

Powell, Anthony V. ^{[1
]}

Chippindale, Ann M.

机构：

[1] Heriot Watt Univ, Dept Chem, Edinburgh EH14 4AS, Midlothian, Scotland

[2] Univ Reading, Sch Chem, Reading RG6 6AD, Berks, England

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2007年 / 68卷 / 5-6期

基金：

英国工程与自然科学研究理事会;

关键词：

chalcogenides; crystal growth; X-ray diffraction;

D O I：

10.1016/j.jpcs.2006.12.010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four new antimony sulphides, [T(dien)(2)]Sb6S10 center dot xH(2)O [T = Ni (1), Co (2) x approximate to 0.45], [Co(en)(3)]SbsSI(3) (3) and [Ni(en)(3)]Sb12S19 (4), have been synthesised under solvothermal conditions. In compounds (1) - (3), Sb12S228- secondary building units are connected to form layered structures. In (1) and (2), Sb-6 S-2- layers containing Sb16S16 heterorings are separated by [T(dien]2](2+) cations, whilst in (3), Sb8 S2- layers 10 13 contain [Co(en)3]2+ cations within large Sb22S22 pores. Compound (4) adopts a three-dimensional structure in which [Ni(en)3 12 cations lie within ca. 5 A wide channels. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：1215 / 1219

页数：5

共 22 条

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