The first structurally characterized organometallic nitrosyl porphyrin: Structure of [Ru(ttp)(NO)(C6H4F-p)] (ttp equals meso-tetratolylporphyrinato dianion)

被引:28
作者
Hodge, SJ
Wang, LS
Khan, MA
Young, VG
RichterAddo, GB
机构
[1] UNIV OKLAHOMA,DEPT CHEM & BIOCHEM,NORMAN,OK 73019
[2] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455
关键词
D O I
10.1039/cc9960002283
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of [Ru(ttp)(NO)Cl] with aryl or alkyl Grignard reagents gives [Ru(ttp)(NO)R](R = C6H4F-p, Me); the Ru-C bond in [Ru(ttp)(NO)Me] undergoes insertion by SO;, and the structure of [Ru(ttp)(NO)(C6H4F-p)] is determined by Xray crystallography.
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页码:2283 / 2284
页数:2
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