Spectroscopic and structural studies on metal halide complexes of 4-vinylpyridine

被引：7

作者：

Bayari, S ^{[1
]}

Ide, S

Yurdakul, S

机构：

[1] Hacettepe Univ, Fac Educ, Dept Phys, TR-06532 Ankara, Turkey

[2] Hacettepe Univ, Fac Engn, Dept Phys, TR-06532 Ankara, Turkey

[3] Gazi Univ, Fac Arts & Sci, Dept Phys, TR-06500 Ankara, Turkey

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2001年 / 560卷 / 1-3期

关键词：

infrared spectra; X-ray powder diffraction; 4-vinylpyridine halide complexes;

D O I：

10.1016/S0022-2860(00)00731-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Fourier transform infrared spectra (4000-400 cm(-1)) are reported for metal(II) halide 4-vinlypridine complexes of the following stoichiometries: [MX2(4-vipy](n) (n = 4, M = Ni, X = Cl or Br; n = 2, M = Cd, X = Cl, Br or I) and assignment are given for all the observed bands. These spectra were compared with X-ray powder diffraction patterns of complexes. It is shown that the proposed structures for these complexes derived from FTIR spectra are consistent with the X-ray powder diffraction measurements and the elemental analysis results. Coordination effect on 4-vinylpyridine has also been investigated. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：95 / 103

页数：9

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