Magnetically separable nanocomposites with photocatalytic activity under visible light for the selective transformation of biomass-derived platform molecules

被引：84

作者：

Balu, Alina M. ^{[1
]}

Baruwati, Babita ^{[2
]}

Serrano, Elena ^{[3
]}

Cot, Jaume ^{[4
]}

Garcia-Martinez, Javier ^{[3
]}

Varma, Rajender S. ^{[2
]}

Luque, Rafael ^{[1
,2
]}

机构：

[1] Univ Cordoba, Dpto Quim Organ, E-14014 Cordoba, Spain

[2] US EPA, Sustainable Technol Div, Natl Risk Management Res Lab, Cincinnati, OH 45268 USA

[3] Univ Alicante, Dept Inorgan Chem, Mol Nanotechnol Lab, E-03690 Alicante, Spain

[4] Inst Quim Avancada Catalunya CID CSIC, Barcelona 08034, Spain

来源：

GREEN CHEMISTRY | 2011年 / 13卷 / 10期

关键词：

DOPED TIO2; TITANIUM-OXIDE; HYDROGEN GENERATION; DEGRADATION; CARBON; FABRICATION; STRATEGIES; OXIDATION;

D O I：

10.1039/c1gc15692f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel magnetically separable TiO2-guanidine-(Ni,Co)Fe2O4 nanomaterials were prepared and characterised by a series of techniques including XRD, SEM, TEM, N-2 physisorption as well as XPS and subsequently tested for their photocatalytic activities in the selective transformation of malic acid in aqueous solution. The modification with guanidine, which remarkably decreases the band gap of the metal oxide, was found to have a significant effect in the photocatalytic activity of the materials under visible light, showing a remarkably superior activity to that of the commercial Degussa P25. These materials are also envisaged to have interesting photocatalytic activities under sunlight.

引用

页码：2750 / 2758

页数：9

共 60 条

[11]

Castello GK, 2010, MATER SCI TECHNOL, P1

[12] Size-controlled synthesis and magnetic properties of NiFe2O4 hollow nanospheres via a gel-assistant hydrothermal route [J].