An electroactive dynamically polydisperse supramolecular dendrimer

被引：106

作者：

Fernandez, Gustavo ^{[1
]}

Perez, Emilio M. ^{[1
]}

Sanchez, Luis ^{[1
]}

Martin, Nazario ^{[1
,2
]}

机构：

[1] Univ Complutense Madrid, Fac Quim, Dept Quim Organ, E-28040 Madrid, Spain

[2] IMDEA Nanociencia, E-28049 Madrid, Spain

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 08期

关键词：

D O I：

10.1021/ja710505h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe the synthesis and supramolecular properties of a bifurcated molecule decorated with two units of an in-house receptor for [60]fullerene, based on the electron donor exTTF, and a PC(61)BA derivative as recognizing units. This monomer self-, assembles to form arborescent and dynamically polydisperse supramolecular aggregates, mainly through pi-pi interactions. This constitutes a fundamentally novel kind of organization of electroactive materials that lies at the interface between dendrimers and supramolecular polymers.

引用

页码：2410 / 2411

页数：2

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