Asymmetric intramolecular C-H insertions of aryldiazoacetates

被引：104

作者：

Davies, HML ^{[1
]}

Grazini, MVA ^{[1
]}

Aouad, E ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 10期

关键词：

D O I：

10.1021/ol0157858

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The enantioselectivity of Rh-2(SDOSP)(4) catalyzed C-H insertion of aryldiazoacetates is very dependent on the site of the C-H insertion. The highest enantioselectivity is obtained for insertion into methine C-H bonds.

引用

页码：1475 / 1477

页数：3

共 19 条

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