Reversible insertion of SO2 into the N-N bond of [Fe-2(CO)(6)(mu-Ph(2)N(2))]

被引：10

作者：

Kabir, SE ^{[1
]}

Ruf, M ^{[1
]}

Vahrenkamp, H ^{[1
]}

机构：

[1] UNIV FREIBURG,INST ANORGAN & ANALYT CHEM,D-79104 FREIBURG,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 512卷 / 1-2期

关键词：

iron; azobenzene; sulphur dioxide; insertion reactions;

D O I：

10.1016/0022-328X(95)05954-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The unusual lability of the N-N bond of the azobenzene ligand in [Fe-2(CO)(6)(mu-Ph(2)N(2))] (1) has allowed the insertion of SO2 under normal conditions. The resulting complex [Fe-2(CO)(6)(mu-PhN-SO2-NPh)] (2) has been shown by structure determination to be a labilized sulphamide derivative. Thermolysis of 2 leads to elimination of SO2 and isolation of [Fe-2(Co)(6)(mu-PhN-Co-NPh)] (3), which is also a thermolysis product of 1.

引用

页码：261 / 263

页数：3

共 19 条

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