Polyaniline based acrylic blends for iron corrosion protection

被引：70

作者：

de Souza, S

da Silva, JEP

de Torresi, SIC

Temperini, MLA

Torresi, RM ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil

[2] Univ Sao Paulo, Inst Quim, BR-05513970 Sao Paulo, Brazil

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 2001年 / 4卷 / 08期

关键词：

D O I：

10.1149/1.1381288

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Coating strategies for corrosion protection considering intrinsically electronic conducting polymers have become important mainly because of restrictions on the use of heavy metals due to their environmental problems. This work presents the electrochemical behavior of an acrylic blend formed by sulfonate-doped polyaniline and poly(methyl methacrylate) used for corrosion protection of iron in chloride solutions. The results would indicate that these blends have a dual protection mechanism; forming a passivating complex with the dopant anion (camphorsulfonate) and simultaneously acting as a physical barrier to avoid chloride anion penetration. (C) 2001 The Electrochemical Society.

引用

页码：B27 / B30

页数：4

共 37 条

[21] ANODIC SYNTHESIS OF POLYANILINE COATINGS ONTO FE SHEETS [J].