The structure of hydrated lead(II) dimethylacetate, [Pb-6(O2CCH(CH3)(2))(12)]4H(2)O: A hexanuclear carboxylate

被引：21

作者：

Fallon, GD

Spiccia, L

West, BO

Zhang, Q

机构：

[1] MONASH UNIV,CTR CHEM SYNTHESIS,CLAYTON,VIC 3168,AUSTRALIA

[2] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

来源：

POLYHEDRON | 1997年 / 16卷 / 01期

关键词：

lead(II); dimethylacetate; carboxylate; structure; Pb-207; NMR;

D O I：

10.1016/0277-5387(96)00275-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrated lead(II) dimethylacetate forms hexanuclear units [Pb-6(O-2-CCH(CH3)(2))(12)]14H(2)O in the solid state consisting of a ring of four lead atoms linked by oxygen atoms belonging to chelated carboxylates, with two further lead atoms linked to the ring by bridging carboxylate oxygens. Water molecules are coordinated to four lead atoms. There are pairs of Pb atoms with 7, 6 and 5-fold coordination in the molecular unit. The hexanuclear molecularity is retained in solution but Pb-207 NMR measurements indicate different 5-coordinate sites are formed. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：19 / 23

页数：5

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