Synthesis and characterization of ruthenium 'pincer' complexes containing sulfur atom donor ligands.: The X-ray crystal structure of [RuCl2(η3-NN′N)(SMe2)] (NN′N = {2,6-(Me2NCH2)2C5H3N})

被引：5

作者：

del Río, I

Gossage, RA

Lutz, M

Spek, AL

van Koten, G

机构：

[1] Univ Utrecht, Debye Inst, Dept Met Mediated Synth, NL-3584 CH Utrecht, Netherlands

[2] Univ Utrecht, Lab Crystal Chem, Bijvoet Ctr Biomol Res, NL-3584 CH Utrecht, Netherlands

来源：

INORGANICA CHIMICA ACTA | 1999年 / 287卷 / 01期

关键词：

crystal structures; ruthenium complexes; pincer complexes; sulfur ligand complexes;

D O I：

10.1016/S0020-1693(98)00418-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of dialkylsulfides or sulfur dioxide with [Ru2Cl4(eta(3)-NN'N)(2)(mu-N-2)] (1: NN'N = {2,6-(Me2NCH2)(2)C5H3N}) leads to the formation of mononuclear complexes of the general formula [RuCl2(eta(3)-NN'N)(eta(1)-SR2)] (SR2 = SMe2, SEt2, C4H8S, SO2). Related dialkyldisulfides and sterically hindered sulfides or thiophenes do not react with 1 or form complicated mixtures of compounds. The X-ray crystal structure of the dimethylsulfide complex [RuCl2(eta(3)-NN'N)(2)(SMe2)], is reported. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：113 / 116

页数：4

共 31 条

[1] Ruthenium-complex-catalyzed N-(cyclo)alkylation of aromatic amines with diols.: Selective synthesis of N-(ω-hydroxyalkyl)anilines of type PhNH(CH2)nOH and of some bioactive arylpiperazines [J].