Synthesis and structural characterisation of platinum silasesquioxane complexes

被引：49

作者：

Abbenhuis, HCL

Burrows, AD

Kooijman, H

Lutz, M

Palmer, MT

van Santen, RA

Spek, AL

机构：

[1] Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands

[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[3] Univ Utrecht, Bijvoet Ctr Biomol Ctr Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 23期

关键词：

D O I：

10.1039/a808130a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of partially condensed silasesquioxanes of the type [(R7Si7O9)-Si-1(OH)(2)(OR2)] (R-1 = c-C5H9, C-C6H11; R-2 = H, SiMe3) with either [Pt(dppe)(CO3)] or [Pt(dppe)Cl-2]/Ag2O leads to the formation of [(R7Si7O9)-Si-1(OR2)O2Pt(dppe)], crystallographically characterised for R-1 = c-C5H9; R-2 = SiMe3, providing unprecedented routes to late transition metal silasesquioxane complexes.

引用

收藏

页码：2627 / 2628

页数：2

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