Molecule-metal interaction of pentacene on copper vicinal surfaces

被引：36

作者：

Baldacchini, Chiara

Allegretti, Francesco

Gunnella, Roberto

Betti, Maria Grazia

机构：

[1] Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy

[2] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England

[3] Univ Camerino, Dipartimento Fis, I-62032 Camerino, MC, Italy

来源：

SURFACE SCIENCE | 2007年 / 601卷 / 13期

关键词：

pentacene; XPS; hybrid interfaces; molecule-metal interaction;

D O I：

10.1016/j.susc.2006.12.016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A combined X-ray photoemission and absorption spectroscopy study of the adsorption of pentacene layers grown on the Cu(119) vicinal surface is presented. A significant interaction between the pi molecular orbitals delocalized on the aromatic rings and the underlying copper substrate is evicted by C 1s core levels manifold peaks at the interface. Adsorption geometry with pentacene molecules almost flat-lying along the Cu terraces is confirmed by the polarization dependence of the C Is absorption features. (C) 2007 Elsevier B.V. All rights reserved.

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页码：2603 / 2606

页数：4

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