Poly[[triapuabis(μ4-3-carboxy-4-hydroxybenzenesulfonato)disilver(I)] monohydrate]

被引:16
作者
Gao, S
Zhu, ZB
Huo, LH
Ng, SW [1 ]
机构
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Heilongjiang Univ, Coll Chem & Mat Sci, Harbin 150080, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷
关键词
D O I
10.1107/S1600536805000504
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the layer structure of the title polymeric complex, {[Ag-2(C7H5O6S)(2)(H2O)(3)] . H2O}(n), both substituted benzenesulfonate anions use two of their sulfonyl O atoms to link to three Ag atoms and their double-bond carbonyl O atom to another Ag atom in a mu(4)-bonding mode. The two symmetry-independent Ag atoms are coordinated by water molecules, one by one water molecule and the other by two water molecules so that one Ag atom is five- and the other six-coordinate.
引用
收藏
页码:M279 / M281
页数:3
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