Oxidative coupling of lithium silenolates: First synthesis of bis(acyl)-substituted polysilanes

被引：23

作者：

Ohshita, J

Masaoka, S

Ishikawa, M

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Hiroshima University

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 09期

关键词：

D O I：

10.1021/om960048e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of lithium 2-meistyl-, adamantyl-, and tert-butyl-1,1-bis(trimethylsilyl)-1-silen-2-olate with 0.5 equiv of palladium dichloride afforded the corresponding coupling products, 1,2-bis(acyl)tetrakis(trimethylsilyl)disilanes (3a-c), in high yields. The molecular structure of compound 3b was established by single-crystal X-ray diffraction study.

引用

页码：2198 / 2200

页数：3

共 13 条

[1]

[Anonymous], CHEM ORGANIC SILIC 1

[2]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[3] RELATIVELY STABLE SILAETHYLENES - PHOTOLYSIS OF ACYLPOLYSILANES [J].