Dendrimers for nanoparticle synthesis and dispersion stabilization

被引:66
作者
Esumi, K [1 ]
机构
[1] Tokyo Univ Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan
[2] Tokyo Univ Sci, Inst Colloid & Interface Sci, Shinjuku Ku, Tokyo 1628601, Japan
来源
COLLOID CHEMISTRY II | 2003年 / 227卷
关键词
dendrimer; metal nanoparticles; semiconductor nanoparticles; nanocomposites;
D O I
10.1007/b10833
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Since dendrimers consisting of regularly branched structure are controlled by chemical structure, molecular weight, and its distribution as well as molecular size and molecular shape, they are unique macromolecules with many functional properties. By using dendrimers as templates, dendrimer-metal nanoparticles are synthesized in aqueous and non-aqueous media. Particle sizes of metals are significantly affected by many factors including concentration of dendrimers and generation of dendrimers. In particular, structure of dendrimer-metal nanoparticles is characterized by TEM, SANS, and SAXS. Synthesis of dendrimer-semiconductor nanoparticles such as CdS and CuS is also described.
引用
收藏
页码:31 / 52
页数:22
相关论文
共 51 条
[41]   A NEW CLASS OF POLYMERS - STARBURST-DENDRITIC MACROMOLECULES [J].
TOMALIA, DA ;
BAKER, H ;
DEWALD, J ;
HALL, M ;
KALLOS, G ;
MARTIN, S ;
ROECK, J ;
RYDER, J ;
SMITH, P .
POLYMER JOURNAL, 1985, 17 (01) :117-132
[42]   STARBURST DENDRIMERS - MOLECULAR-LEVEL CONTROL OF SIZE, SHAPE, SURFACE-CHEMISTRY, TOPOLOGY, AND FLEXIBILITY FROM ATOMS TO MACROSCOPIC MATTER [J].
TOMALIA, DA ;
NAYLOR, AM ;
GODDARD, WA .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1990, 29 (02) :138-175
[43]   Au(III)-PAMAM interaction and formation of Au-PAMAM nanocomposites in ethyl acetate [J].
Torigoe, K ;
Suzuki, A ;
Esumi, K .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2001, 241 (02) :346-356
[44]   Self-assembled multilayer films from dendrimers [J].
Tsukruk, VV ;
Rinderspacher, F ;
Bliznyuk, VN .
LANGMUIR, 1997, 13 (08) :2171-2176
[45]   CDS NANOCLUSTERS - SYNTHESIS, CHARACTERIZATION, SIZE-DEPENDENT OSCILLATOR STRENGTH, TEMPERATURE SHIFT OF THE EXCITONIC-TRANSITION ENERGY, AND REVERSIBLE ABSORBENCY SHIFT [J].
VOSSMEYER, T ;
KATSIKAS, L ;
GIERSIG, M ;
POPOVIC, IG ;
DIESNER, K ;
CHEMSEDDINE, A ;
EYCHMULLER, A ;
WELLER, H .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (31) :7665-7673
[46]   Dendrimers in supramolecular chemistry: From molecular recognition to self-assembly [J].
Zeng, FW ;
Zimmerman, SC .
CHEMICAL REVIEWS, 1997, 97 (05) :1681-1712
[47]   Preparation of Cu nanoclusters within dendrimer templates [J].
Zhao, MQ ;
Sun, L ;
Crooks, RM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (19) :4877-4878
[48]   Intradendrimer exchange of metal nanoparticles [J].
Zhao, MQ ;
Crooks, RM .
CHEMISTRY OF MATERIALS, 1999, 11 (11) :3379-3385
[49]  
Zhao MQ, 1999, ANGEW CHEM INT EDIT, V38, P364, DOI 10.1002/(SICI)1521-3773(19990201)38:3<364::AID-ANIE364>3.0.CO
[50]  
2-L