Phase diagram of half doped manganites

被引:23
作者
Brey, L [1 ]
机构
[1] CSIC, Inst Ciencia Mat Madrid, E-28049 Madrid, Spain
关键词
D O I
10.1103/PhysRevB.71.174426
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
An analysis of the properties of half doped manganites is presented. We buildup the phase diagram of the system combining a realistic calculation of the electronic properties and a mean field treatment of the temperature effects. The electronic structure of the manganites are described with a double exchange model with cooperative Jahn-Teller phonons and antiferromagnetic coupling between the Mn core spins. At zero temperature a variety of electronic phases as f6rromagnetic (FM) charge ordered (CO) orbital ordered (00), CE-CO-OO and FM metallic, are obtained. By raising the temperature the CE-CO-OO phase becomes paramagnetic (PM), but depending on the electron-phonon coupling and the exchange coupling the transition can be direct or through intermediate states: a FM disorder metallic, a PM-CO-OO or a FM-CO-OO. We also discuss the nature of the high temperature PM phase in the regime of finite electron phonon coupling. In this regime half of the oxygen octahedra surrounding the Mn ions are distorted. In the weak coupling regime the octahedra are slightly deformed and only trap a small amount of electronic charge, rendering the system metallic consequentially. However, in the strong coupling regime the octahedra are strongly distorted, the charge is fully localized in polarons and the system is insulator.
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页数:9
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共 38 条
[21]   Weak charge-lattice coupling requires reinterpretation of stripes of charge order in La1-xCaxMnO3 -: art. no. 097202 [J].
Loudon, JC ;
Cox, S ;
Williams, AJ ;
Attfield, JP ;
Littlewood, PB ;
Midgley, PA ;
Mathur, ND .
PHYSICAL REVIEW LETTERS, 2005, 94 (09)
[22]   Charge-ordered ferromagnetic phase in La0.5Ca0.5MnO3 [J].
Loudon, JC ;
Mathur, ND ;
Midgley, PA .
NATURE, 2002, 420 (6917) :797-800
[23]  
MATHUR N, 2001, SOLID STATE COMMUN, V119, P1509
[24]   Electronically soft phases in manganites [J].
Milward, GC ;
Calderón, MJ ;
Littlewood, PB .
NATURE, 2005, 433 (7026) :607-610
[25]  
MORI NCS, 1959, PHYS REV B, V59, P13573
[26]   Competing orders and disorder-induced insulator to metal transition in manganites [J].
Motome, Y ;
Furukawa, N ;
Nagaosa, N .
PHYSICAL REVIEW LETTERS, 2003, 91 (16) :167204-167204
[27]   Charge, orbital, and magnetic ordering in La0.5Ca0.5MnO3 [J].
Radaelli, PG ;
Cox, DE ;
Marezio, M ;
Cheong, SW .
PHYSICAL REVIEW B, 1997, 55 (05) :3015-3023
[28]   Phase competition in L0.5A0.5MnO3 perovskites -: art. no. 174432 [J].
Rivadulla, F ;
Winkler, E ;
Zhou, JS ;
Goodenough, JB .
PHYSICAL REVIEW B, 2002, 66 (17) :1744321-17443210
[29]   Coexistence of paramagnetic-charge-ordered and ferromagnetic-metallic phases in La0.5Ca0.5MnO3 evidenced by electron spin resonance [J].
Rivadulla, F ;
Freita-Alvite, M ;
López-Quintela, MA ;
Hueso, LE ;
Miguéns, DR ;
Sande, P ;
Rivas, J .
JOURNAL OF APPLIED PHYSICS, 2002, 91 (02) :785-788
[30]   LOW-TEMPERATURE MAGNETORESISTANCE AND THE MAGNETIC PHASE-DIAGRAM OF LA1-XCAXMNO3 [J].
SCHIFFER, P ;
RAMIREZ, AP ;
BAO, W ;
CHEONG, SW .
PHYSICAL REVIEW LETTERS, 1995, 75 (18) :3336-3339