A deprotection strategy of a BODIPY conjugated porous polymer to obtain a heterogeneous (dipyrrin)(bipyridine)ruthenium(II) visible light photocatalyst

被引：57

作者：

Liras, Marta ^{[1
]}

Pintado-Sierra, Mercedes ^{[1
]}

Iglesias, Marta ^{[2
]}

Sanchez, Felix ^{[1
]}

机构：

[1] CSIC, Inst Quim Organ Gen, Juan Cierva 3, E-28006 Madrid, Spain

[2] CSIC, ICMM, Sor Juana Ines de la Cruz 3, Madrid 28049, Spain

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2016年 / 4卷 / 44期

关键词：

MICROPOROUS POLYMERS; COMPLEXES; DYE; SENSITIZERS; DIPYRRINS; OXIDATION; BINDING;

D O I：

10.1039/c6ta07696c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This work shows that a deprotection strategy of BODIPY conjugated porous polymers (CMPBDPs) can be successfully applied to synthesize a new (dipyrrin)(bipyridine)Ru(II) (CMPBDP-Ru) efficient heterogeneous photocatalyst for iminium ion generation under visible light. CMPBDP-Ru shows high thermal and photochemical stability under irradiation, and it could be reused several times.

引用

页码：17274 / 17278

页数：5

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