Conjugated microporous poly (aryleneethynylene) networks

被引：1322

作者：

Jiang, Jia-Xing

Su, Fabing

Trewin, Abbie

Wood, Colin D.

Campbell, Nell L.

Niu, Hongjun

Dickinson, Calum

Ganin, Alexey Y.

Rosseinsky, Matthew J.

Khimyak, Yaroslav Z.

Cooper, Andrew I.

机构：

[1] Univ Liverpool, Dept Chem, Liverpool, Merseyside, England

[2] Univ Liverpool, Ctr Mat Discovery, Liverpool L69 3BX, Merseyside, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 45期

关键词：

conjugation; microporous materials; networks; polymerization;

D O I：

10.1002/anie.200701595

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Rigid wiry nets: Conjugated microporous polymer networks are formed by Sonogashira-Hagihara coupling. Although these materials are amorphous, the micropore size and surface area can be controlled by varying the length of the phenyleneethynylene struts (see picture; the network is shown in blue, and one 1,3,5-substituted benzene node and three connected struts are highlighted with C gray and H white). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8574 / 8578

页数：5

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