Palladium catalysed cascade bis-cyclisation-anion capture processes proceeding via allenyl-palladium(II) starter species. 1-vinyl-3-azabicyclo[3.1.0]hexanes.

被引:61
作者
Grigg, R [1 ]
Rasul, R [1 ]
Redpath, J [1 ]
Wilson, D [1 ]
机构
[1] ORGANON LABS,NEWHOUSE ML1 5SH,LANARK,SCOTLAND
关键词
D O I
10.1016/0040-4039(96)00889-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An additional starter species [allenylpalladium(II)] has been implemented for palladium catalysed cascade cyclisation-anion capture processes. Good yields of bis-cyclisation-anion products involving anionic (NaBPh(4)), neutral (CO/MeOH) and organometallic (Bu(3)SnR) capture agents are reported. Copyright (C) 1996 Elsevier Science Ltd
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页码:4609 / 4612
页数:4
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