Preparation and characterization of multiwalled carbon nanotube/poly(3-hexylthiophene) thermoelectric composite materials

被引：54

作者：

Du, Y. ^{[1
,2
]}

Shen, S. Z. ^{[2
]}

Yang, W. D. ^{[2
]}

Cai, K. F. ^{[1
]}

Casey, P. S. ^{[2
]}

机构：

[1] Tongji Univ, Funct Mat Res Lab, Shanghai 200092, Peoples R China

[2] CSIRO, Mat Sci & Engn Div, Clayton, Vic 3169, Australia

来源：

SYNTHETIC METALS | 2012年 / 162卷 / 3-4期

基金：

中国国家自然科学基金;

关键词：

Poly(3-hexylthiophene); Multiwalled carbon nanotube; Thermoelectric properties; Composite; NANOTUBES; BEHAVIOR;

D O I：

10.1016/j.synthmet.2011.12.023

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Multiwalled carbon nanotube/poly(3-hexylthiophene) (MWCNT/P3HT) composites were prepared by oxidative polymerization of 3-hexylthiophene in a MWCNTs dispersed chloroform solution. The phase composition of the composite materials was analyzed by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). The thermoelectric properties of the composite powders, after cold pressing into pellets, were measured at temperatures between 293 and 423 K. The electrical conductivity of samples containing 30 wt% MWCNT displayed a gradual decrease in conductivity from 0.13 to 0.11 S/cm across this temperature range and was accompanied by an increased in the Seebeck coefficient from 9.7 to 11.3 mu V/K. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：375 / 380

页数：6

共 27 条

[21] Turning Carbon Nanotubes from Exceptional Heat Conductors into Insulators [J].

Prasher, Ravi S. ;

Hu, X. J. ;

Chalopin, Y. ;

Mingo, Natalio ;

Lofgreen, K. ;

Volz, S. ;

Cleri, F. ;

Keblinski, Pawel .

PHYSICAL REVIEW LETTERS, 2009, 102 (10)

[22] Synthesis and characterization of new 3-alkylthiophene copolymer that exhibit orange-red photoluminescence and electroluminescence [J].

Qi, Zheng-jian ;

Feng, Wei-dong ;

Sun, Yue-ming ;

Yan, Da-zhi ;

He, Yan-fang ;

Yu, Jing .

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2007, 18 (08) :869-875

[23] Mesoscopic thermal and thermoelectric measurements of individual carbon nanotubes [J].

Small, JP ;

Shi, L ;

Kim, P .

SOLID STATE COMMUNICATIONS, 2003, 127 (02) :181-186

[24] A three-in-one improvement in thermoelectric properties of polyaniline brought by nanostructures [J].

Sun, Yirneng ;

Wei, Zhongming ;

Xu, Wei ;

Zhu, Daoben .

SYNTHETIC METALS, 2010, 160 (21-22) :2371-2376

[25] Thermal transporting properties of electrically conductive polyaniline films as organic thermoelectric materials [J].

Yan, H ;

Sada, N ;

Toshima, N .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2002, 69 (03) :881-887

[26] Enhanced Thermoelectric Performance of Single-Walled Carbon Nanotubes/Polyaniline Hybrid Nanocomposites [J].

Yao, Qin ;

Chen, Lidong ;

Zhang, Wenqing ;

Liufu, Shengcong ;

Chen, Xihong .

ACS NANO, 2010, 4 (04) :2445-2451

[27] Thermoelectric Behavior of Segregated-Network Polymer Nanocomposites [J].

Yu, Choongho ;

Kim, Yeon Seok ;

Kim, Dasaroyong ;

Grunlan, Jaime C. .

NANO LETTERS, 2008, 8 (12) :4428-4432

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