Preparation and synthetic applications of α-fluorovinylphosphonium salts

被引：13

作者：

Hanamoto, T ^{[1
]}

Kiguchi, Y ^{[1
]}

Shindo, K ^{[1
]}

Matsuoka, M ^{[1
]}

Kondo, M ^{[1
]}

机构：

[1] Saga Univ, Dept Chem, Honjyo, Saga 8408502, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 02期

关键词：

D O I：

10.1039/a807933a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

alpha-Fluorovinylphosphonium salts 3 and 4 were synthesized and underwent Michael addition followed by Wittig olefination to give the corresponding monofluoroethylene compounds in good yields.

引用

页码：151 / 152

页数：2

共 15 条

[1] SYNTHESIS OF ALPHA-FLUOROVINYLPHOSPHONATES [J].

BLACKBURN, GM ;

PARRATT, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (08) :1417-1424

[2] THE SYNTHESIS OF ALPHA-FLUOROVINYLPHOSPHONATES [J].

BLACKBURN, GM ;

PARRATT, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (21) :1270-1271

[3] 1-DIPHENYLPHOSPHONIO-1-METHOXYMETHYLLITHIUM, A USEFUL REAGENT FOR THE SYNTHESIS OF ALDEHYDES FROM HINDERED KETONES [J].

COREY, EJ ;

TIUS, MA .

TETRAHEDRON LETTERS, 1980, 21 (37) :3535-3538

[4] On the preparation and unusual reactivity of a potential difluorodienophile [J].

Crowley, PJ ;

Percy, JM ;

Stansfield, K .

TETRAHEDRON LETTERS, 1996, 37 (45) :8233-8236

[5] Diels-Alder reactions of vinyl fluorides with 1,3-diphenylisobenzofuran [J].

Ernet, T ;

Haufe, G .

TETRAHEDRON LETTERS, 1996, 37 (40) :7251-7252

[6] The stereoselective preparation of cis and trans-1,2-difluoroethylene synthons [J].

Fontana, SA ;

Davis, CR ;

He, YB ;

Burton, DJ .

TETRAHEDRON, 1996, 52 (01) :37-44

[7] PREPARATION AND CRYSTAL-STRUCTURE OF A PARENT 1-ARYLBENZO[B]THIOPHENIUM TRIFLATE AND ITS DERIVATIVES [J].

KITAMURA, T ;

YAMANE, M ;

FURUKI, R ;

TANIGUCHI, H ;

SHIRO, M .

CHEMISTRY LETTERS, 1993, (10) :1703-1706

[8] 1-phenyl-1-benzothiophenium triflates by a direct S-phenylation with diphenyliodonium triflate [J].

Kitamura, T ;

Yamane, M ;

Zhang, BX ;

Fujiwara, Y .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1998, 71 (05) :1215-1219

[9] NUCLEOPHILIC REACTIONS OF FLUOROOLEFINS . EVIDENCE FOR A CARBANION INTERMEDIATE IN VINYL AND ALLYL DISPLACEMENT REACTIONS [J].

KOCH, HF ;

KIELBANI.AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (03) :729-&

[10] Stereospecific synthesis of 1-fluoro olefins via (fluorovinyl)stannanes and an unequivocal NMR method for the assignment of fluoro olefin geometry [J].

McCarthy, JR ;

Huber, EW ;

Le, TB ;

Laskovics, FM ;

Matthews, DP .

TETRAHEDRON, 1996, 52 (01) :45-58

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